Hundreds of business and community leaders are expected to attend the Superstars in Business luncheon today at the Hotel DuPont.   The 14th annual event sponsored by the Delaware State Chamber of Commerce will feature awards for achievements by small businesses and non-profits.  This year's winners include Blooming Boutique, Cover & Rossiter, P.A., Emory Hill Companies and the Blood Bank of Delmarva.  Award-winning chef and owner of Piccolina Toscana, Deep Blue and other area restaurants Dan Butler will be the keynote speaker.